Since
their discovery 14 years ago, carbon nanotubes have
captured the imagination of scientists and lay people
alike. The science of nanotubes almost seems more
science fiction than science. These structures, so
minuscule they cannot be seen, are stronger than
diamonds. They are formed from organic material but
act as metals or semi-conductors. As such, nanotubes
offer great potential in electronics, lasers and
medicine.
To highlight the status of research on nanotubes,
Slava V. Rotkin and Shekhar Subramoney have edited
a new book, "Applied Physics of Carbon Nanotubes:
Fundamentals of Theory, Optics and Transport Devices," which
was just released by Springer. The book's 12 chapters
are written by top researchers in the field.
Rotkin is an assistant professor of physics and
a faculty member with Lehigh's Center for Advanced
Materials and Nanotechnology. Subramoney, a researcher
with Dupont Central Research and Development Laboratories,
is co-chair of the nanotube section of the Fullerenes,
Nanotubes and Carbon Nanostructures Division of the
Electrochemical Society Inc.
The book offers basic information about the properties
and characterization of nanotubes as well as information
about new research tools, like nanotube optical spectroscopy,
some of which are only 18 months old. With its emphasis
on applications, the book is intended for scientists,
engineers and investors.
Nanotubes are sheets of carbon atoms connected in
a honeycomb-like pattern that are rolled into tiny
cylinders one nanometer in diameter. One nanometer
is one one-billionth of a meter, or one 10,000th
the thickness of a human hair. The properties of
the tube depend on how the cylinder is rolled, just
as the properties of chemical elements depend on
their weight.
Rotkin and Subramoney's book covers four main areas
of nanotube research: theories and modeling, synthesis
and characterization, optical spectroscopy, and transport
and electromechanical applications.
The first section, on the theories and modeling
of nanotubes, includes a chapter by Rotkin titled "From
Quantum Models to Novel Effects to New Applications:
Theory of Nanotube Devices." Rotkin's research has
focused on designing a novel type of electronic switch
called a metallic field-effect transistor. He reported
a breakthrough in this area in an article in Applied
Physics Letters last year.
In the second section, readers learn about nanotube
properties, which vary widely, and about how nanotubes
are made, identified and classified. Given the right
chemical conditions, nanotubes grow on their own.
So far, the longest nanotubes created have been measured
in centimeters.
The third section describes new work on the use
of optical spectroscopy to study nanotechnology.
This revolutionary new method, Rotkin says, uses
light to identify the properties of a nanotube. The
progress in nanotube synthesis, their separation
and research in optical spectroscopy will result
in developing "robust tools to bring nanotubes to
the tables of engineers," he says.
Optical spectroscopy allows researchers to study
how nanotubes "breathe," or vibrate, by regularly
expanding and contracting. Like fingerprints, each
nanotube has a unique pulse. The pulsing nanotubes
reflect light waves like a car reflects the sound
waves from a police radar gun. As the radar gun measures
a car's speed by the frequency of the sound waves
it reflects, scientists determine the pulse of nanotubes
by measuring the frequency of the light waves they
give off. From the pulse they can then identify a
nanotube's properties even if it is invisible.
The final section of the book discusses electronic
applications of nanotubes. Although uses of nanotubes
are only just beginning to explored, the field holds
great promise. Already, Samsung electronics and Motorola
are using nanotubes in flat panel display screens.
Nanotube field emitters are "better, cheaper and
longer lasting" than the metal tip emitters used
before, Rotkin says.
"Electronic applications of nanotubes in their childhood," Rotkin
says, "are much, much better than silicon devices
were in their childhood."
Nanotubes, which emit light, may also be used for
lasers and other optoelectronic devices. Scientists
believe the nanotubes could increase the range of
laser power, making them useful for detecting chemical
and biological weapons.
Another chapter discusses the mechanical properties
and future uses of nanotubes. Some scientists believe
that nanotubes could be used for a space elevator.
Nanotubes are the only material strong enough to
support an elevator extending miles into space from
the earth's surface. If scientists can make a nanotube
long enough, then the elevator would be possible.
Nanotubes could also be used to treat sickle-cell
anemia and other diseases resulting from malfunctioning
ion channels. Since all living organisms are constructed
from carbon, the nanotubes would not be rejected
by the body.
The book contains a chapter on DNA and nanotube
interactions that was written by Anand Jagota, professor
of chemical engineering and director of Lehigh's
bioengineering and life sciences program. When nanotubes
are created, they form a dense clump, like a box
of uncooked spaghetti noodles, Rotkin says. To separate
nanotubes, researchers originally added soap, which
peeled nanotubes apart. Then strong acceleration
caused the heavier nanotubes to fall and the smaller
ones to float.
The process worked but not without drawbacks. The
soap chemically changes nanotubes. Jagota and other
researchers are looking for other ways to separate
nanotubes. By wrapping DNA and proteins around the
nanotubes, Jagota achieved the same result as soap
without the chemical difficulties.
Jagota's work in this area complements Rotkin's
current investigations into the theoretical aspects
of DNA-nanotube interactions |