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An
incredibly sensitive Cornell apparatus probes the
mystery of a high-temperature superconductor
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In
a standard scanning tunneling microscope image, left,
the atoms in a cuprate crystal the bright blobs) are
not in a particularly orderly arrangement. But an
image of the probable distribution of electrons, right,
shows that clouds of them have arranged themselves
in what amounts to an electronic crystal. The brighter
areas seem to contain more electrons, but the reason
for this is unknown |
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ITHACA,
N.Y. -- With equipment so sensitive that it can locate
clusters of electrons, Cornell University and University
of Tokyo physicists have -- sort of -- explained puzzling
behavior in a much-studied high-temperature superconductor,
perhaps leading to a better understanding of how such
superconductors work.
It turns out that under certain conditions the electrons
in the material pretty much ignore the atoms to which
they are supposed to be attached, arranging themselves
into a neat pattern that looks like a crystal lattice.
The behavior occurs in a phase physicists have called
a "pseudogap," but because the newly discovered
arrangement looks like a checkerboard in scanning
tunneling microscope (STM) images, J.C. Séamus
Davis, Cornell professor of physics, calls the phenomenon
a "checkerboard phase."
Davis, Hidenori Takagi, professor of physics at the
University of Tokyo, and co-workers describe the observations
in the Aug. 26, 2004, issue of the journal Nature.
An article about the work also is scheduled to appear
in the September issue of Physics Today.
"In at least one cuprate high-temperature superconducting
material that phase is an electronic crystal,"
Davis reports. "We don't understand what we've
found, but we have moved into unknown territory that
everyone has wanted to explore. Many people have believed
that to understand high-temperature superconductivity
we have to look in this territory."
A superconductor is a material capable of conducting
electricity with virtually no resistance. Modified
crystals of copper oxide, known as cuprates, can become
superconductors at temperatures up to about 150 Kelvin
(-123 degrees Celsius or --253 degrees Fahrenheit)
when they are doped with other atoms that create "holes"
in the crystal structure where electrons would ordinarily
be. These superconductors are widely used in industry,
although there is still no clear explanation of how
they work. Their superconducting behavior begins when
about 10 percent of the electrons have been removed,
but for over a decade physicists have been puzzled
by what happens when somewhat fewer electrons are
removed: The material conducts electricity, but just
barely. In theory it shouldn't conduct at all.
Davis has now been able to observe this phase with
a specially modified STM that measures, in effect,
the quantum wave functions of the electrons in a sample.
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Cornell
post-docs Yuki Kohsaka and Christian Lupien and
Professor J.C. Séamus Davis are flanked in
the STM lab by the massive supports of a modified
scanning tunnelling microscope,
so sensitive that it can resolve details smaller
than atoms. Frank DiMeo/Cornell University
Photography Copyright ©
Cornell University
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| The
famous Heisenberg uncertainty principle says that we
can never tell exactly where an electron is. Rather
than thinking of electrons orbiting the nuclei of atoms
like little planets, scientists today imagine "clouds"
of electrons somewhere in the vicinity. An STM uses
a needle so fine that its tip consists of just one atom,
scanning across a small surface and measuring current
flow between the surface and the tip. Conventional STMs
scan with enough precision to image individual atoms.
Davis has increased the scanning precision to a point
where he can resolve details smaller than atoms. His
new instrument, located in the basement of the Clark
Hall of Science on the Cornell campus, is so sensitive
that it has been built in a room mounted on heavy concrete
pillars and isolated by air springs. For these experiments,
it scans a sample and reads the probability that electrons
are in certain locations, based on current flow through
the STM tip. |

To
protect the instrument from outside vibrations,
the modified STM at Cornell is enclosed in a sealed,
isolated room mounted on massive supports.
Copyright © Cornell
University
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Davis's
team studied a copper oxide containing calcium and
chlorine that was doped by replacing some of the calcium
atoms with sodium to remove, in various samples, from
8 to 12 percent of the electrons. The material was
cooled to about 100 milliKelvins, or a hundredth of
a degree above absolute zero.
What they found was that the electrons in the sample
arranged themselves in tiny squares, all in turn arranged
in a neat checkerboard pattern. The same pattern was
found at the highest level of doping tested, where
the material begins to become superconducting. Whether
or not it continues at higher levels remains to be
seen, Davis says
.
The discovery only leads to more questions. Theoretically,
Davis says, this arrangement should not conduct electricity
at all, because the electrons are locked into their
crystal-like pattern. "It's always been a mystery,
how do you get from an insulator through a tiny change
to a superconductor," he notes. "Having
empirical knowledge of what this phase is may help
us to get from here to there."
The Nature paper is titled "Discovery of a 'Checkerboard'
Electronic Crystal State in Lightly Hole-Doped Ca2-xNaxCuO2Cl2."
Along with Davis and Takagi, co-authors include Cornell
post-doctoral researchers Christian Lupien and Yuki
Kohsaka; Dung-Hai Lee, University of California-Berkeley
professor of physics; and Tetsuo Hanaguri of the RIKEN
Institute in Japan. The cuprate material used in the
experiments were prepared by Yuki Kohsaka at the University
of Tokyo in collaboration with the scientists who
developed it in 1995, Masaki Azuma and Mikio Takano
of Kyoto University.
Related World Wide Web sites: The following sites
provide additional information on this news release.
Some might not be part of the Cornell University community,
and Cornell has no control over their content or availability.
• Séamus Davis: http://www.physics.cornell.edu/profpages/Davis.htm |
www.nano-tsunami.com
This
story has been adapted from a news release -
Diese Meldung basiert auf einer Pressemitteilung
-
Deze
tekst is gebaseerd op een nieuwsbericht -
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