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The World's Smallest Fountain Pen?

New microscope tips use capillary action to print patterns tens of nanometers across

 

The new nanofountain probe produced these patterns; features are as thin as 40 nanometers.

The miniscule tip on an atomic-force microscope (AFM) helps researchers both "see" and manipulate the nanoscale environment. Now, engineers have created two novel technologies that enable such tips to write features as small as viruses and to withstand abuse with the resilience of diamond. Eventually, they believe, vast arrays of such nanofountain probes could prove useful for crafting such intricate systems as protein arrays or complex semiconductors.

By taking advantage of the same capillary forces that keep fountain pens flowing, researchers from Northwestern University in Evanston, Ill., created a specialized structure that channels inks from a tiny reservoir down to a miniscule AFM tip.

Existing "dip-pen" techniques utilize the same inks, which range from pigments for creating patterns to organic materials for creating sensors, but they suffer from difficulties with maintaining a regular ink supply. The new "nanofountain probe" can paint features as small as 40 nanometers and carries its own ink reservoir.

Horacio Espinosa and colleagues from the NSF Nanoscale Science and Engineering Center for Integrated Nanopatterning and Detection Technologies crafted the probe using standard microfabrication techniques, so device production is scalable.

The center, a collaboration among researchers from Northwestern University, the University of Chicago, the University of Illinois at Urbana-Champaign and Argonne National Laboratory, was also behind the development of another AFM breakthrough, single-piece, ultra-nano-crystalline diamond cantilevers and tips.

Existing commercially available tips incorporate a diamond tip glued to a cantilever, a difficult component to craft, or less durable silicon tips coated with layers of diamond.

In addition to being extremely durable, the new tips are also crafted using standard microfabrication techniques and offer the same manufacturing advantages as the nanofountain probes.

Both developments appeared in the journal Small. A report on the nanofountain probe appeared in the April 2005 issue, and one on the ultra-nano-crystalline diamond tip appeared in the August 2005 issue.

The research was supported by NSF Grants 0304472 and 0118025

-- Josh Chamot

Investigators
Zhen Chen
Chad Mirkin
Mark Hersam
Ted Belytschko
Horacio Espinosa
Orlando Auciello

Related Institutions/Organizations
Northwestern University
Argonne National Laboratory
University of Missouri-Columbia

Locations
NSF Nanoscale Science and Engineering Center for, Illinois

Related Awards
#0118025 Nanoscale Science & Engineering Center for Integrated Nanopatterning and Detection Technologies
#0304472 NIRT: Science and Technology of Ultrananocrystalline Diamond Films for Multifunctional MEMS/NEMS Devices

Total Grants
$1,300,001

Related Agencies
Department of Energy


This scanning electron micrograph shows the new nanofountain-probe dispensing tip.

Credit: © 2005 Horacio D. Espinosa

The scanning electron micrograph shows a nanofountain-probe chip, including cantilevers and the on-chip reservoir.

Credit: © 2005 Horacio D. Espinosa

 

This slide highlights the components and features of the nanofountain probe (NFP). (a) The schematic illustrates the NFP writing mechanism. A molecular ink drawn from an on-chip reservoir forms a liquid air interface at the aperture of the volcano-like dispensing tip. Molecules diffuse from the interface to a substrate and capillary condensation forms a water meniscus. (b) This schematic shows how capillary force delivers liquid from the reservoir to the dispensing tip. (c) The scanning electron micrograph shows an NFP dispensing tip. (d) The scanning electron micrograph of the NFP chip shows cantilevers and an on-chip reservoir. (e) The scanning electron micrograph shows an NFP linear array. Insets show blow-ups of a dispensing tip at the end of a cantilever. (f) These are frictional atomic force microscopy images of features patterned by an NFP. Patterns have line widths as thin as 40 nm.

Credit: © 2005 Horacio D. Espinosa

This slide highlights the ultra-nano-crystalline diamond (UNCD) atomic force microscope (AFM)cantilever. (a) This is a scanning-electron micrograph of a UNCD cantilever with a tip. (b) This is a scanning electron micrograph of a UNCD tip after one hour of scanning on a diamond substrate. Inset shows the tip before the scanning. (c) This is a frictional AFM image of an alkanethiol monolayer patterned onto a gold substrate with a UNCD tip. Researchers used the same tip for patterning and imaging. (d) This scanning electron micrograph shows a commercially available silicon nitride tip after one hour of scanning with the same parameters used for the UNCD tip in (b). The image shows damage at the tip apex while the inset shows the tip prior to the test.

Credit: © 2005 Horacio D. Espinosa

 

This story has been adapted from a news release -
Diese Meldung basiert auf einer Pressemitteilung -
Deze tekst is gebaseerd op een nieuwsbericht -





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